Nitrene transfer reactions catalyzed by gold complexes.
نویسندگان
چکیده
We report here the first gold-catalyzed nitrene transfer reaction. A gold(I) compound, supported by 4,4',4' '-tri-tert-butyl-2,2':6',2' '-terpyridine (tBu3tpy) as the ligand, efficiently catalyzes olefin aziridination with the use of the commercially available oxidant PhI(OAc)2 and sulfonamides. This system also mediates carbene insertion into benzene.
منابع مشابه
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ورودعنوان ژورنال:
- The Journal of organic chemistry
دوره 71 16 شماره
صفحات -
تاریخ انتشار 2006